Wroclaw itself is the best part (the architecture), and here are some recommended sites:
Ostrow Tumski - Island where city began
Museum of Architecture - bldg itself is cool; stained glass, gargoyles, old tile stoves, etc. had a special exhibit of modern italian product design when I visited that alone was worth it
University - swordsman statue out front; ceremonial hall inside is truly impressive
Cathedral of St. John the Baptist
The Panorama (Tapestry) - sadly closed when I visited, everyone in W. will tell you to see it
Nat'l Museum (of Art) - b/c I love art; lots of the usual old religious carvings & paintings, but the modern collection is excellent and fascinating after you've seen one too many carved Madonnas
Hala Targowa - large indoor market hall with the usual produce, baked stuff, butcher,s etc. and a very popular little restaurant just inside the door - pop w/students from univ and babushkas alike... fun to just wander through.
Have fun.
ps--different feel from Krakow, though of course there are similarities (i.e. univ students everywhere, architecture) etc.)
pps--"Le Bistrot Parisien" is a cool little spot for a crepe w/side of Polish-style French atmosphere; there's a Coffee Planet right on the rynek that's a great place to sit & watch world walk by the big windows--good coffee & artsy feel inside; but v. popular