flight from la paz to santiago

I really dont think there are direct flights from La Paz to Santiago. But you can maybe find cheap tickets (with 1 stop over) with SKY AIRLINES.
You may also check LAN but the price is going to be higher .

There is a difference between a non-stop flight and a direct flight. If your flight makes a stop in northern Chile, you should go through passport control and customs there. Check with the airline about this. If you fly directly into SCL on an international flight (your profile says you are from Australia) you will have to pay a reciprocity fee of US$117 per person.

Sky Airlines have by far the best fares to SCL but the plane stops in Arica and Iqueque. Femby makes a good point that you will probably have to pay the reciprocity fee because you don't actually get off the plane in those stopovers. You could contact SKY to confirm

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