I discovered this fairly long list of ghana-related NGOs that might be of use to someone researching volunteer placements:
http://www.ghanaweb.com/GhanaHomePage/directory/cat30.html
click on 'foreign' or 'local'.
I can't vouch for any of these but perhaps you'll find some alternatives to the bigger names in the business.
It goes without saying: take care paying any money in advance - most will happily take your money once in Ghana.
